Exercise 1Question 1
Which of the ores mentioned in Table 6.1 can be concentrated by magnetic separation method?
Exercise 1Question 3
The reaction,
Cr2O3 + 2Al → Al2O3 + 2Cr (ΔGo = -421kJ)
is thermodynamically feasible as is apparent from the Gibbs energy value. Why does it not take place at room temperature?
Exercise 1 Question 4
Is it true that under certain conditions, Mg can reduce SiO2 and Si can reduce MgO? What are those conditions?
Exercise 2 Question 3
Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?
Exercise 2 Question 6
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present ?
Exercise 2Question 11
What criterion is followed for the selection of the stationary phase in chromatography?
Exercise 2Question 14
The value of ΔfGø for formation of Cr2O3 is - 540 kJmol-1 and that of Al2 O3 is - 827 kJmol-1. Is the reduction of Cr2O3 possible with Al?
Exercise 2 Question 16
The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement? Support your opinion with two examples.
Exercise 2 Question 17
Name the processes from which chlorine is obtained as a by-product. What will happen if an aqueous solution of NaCl is subjected to electrolysis?
Exercise 2 Question 18
What is the role of graphite rod in the electrometallurgy of aluminium?
Exercise 2 Question 19
Outline the principles of refining of metals by the following methods:
(i) Zone refining
(ii) Electrolytic refining
(iii) Vapour phase refining
Question 22
How can you separate alumina from silica in bauxite ore associated with silica? Give equations, if any.